OSU Chemistry Polymers Option



Typical topics to be considered toward a satisfactory coverage of the lecture and laboratory components of the polymers curriculum.

LECTURE COMPONENT

I. Basic Aspects of Materials Science

Bonding, Crystalline and Non-crystalline Structures
Thermal and Mechanical Properties
Major Types of Materials and Comparative Analysis - Metals, Ceramics, Polymers, Semi-conductors and Composites

II. Synthesis and Characterization of Polymers and Their Intermediates Synthesis and Characterization of Monomers and Intermediates
Formation of Different Types of Polymers and Polymerization Methods and Pertinent Mechanisms
Copolymers and Copolymerization
Polymerization Kinetics
Structure and Properties of Polymers - Structural Analysis, Solution Properties, Molecular Dimensions

III. Polymers as Reactive Substrates Polymer Reaction and Modification
Polymer Degradation

IV. Polymers as Solid Materials Major Types - Thermoplastics, Thermosets, Elastomers
Thermal and Electrical Properties
Morphology of Ordered and Disordered Structures
Polymer Rheology
Mechanical Properties of Polymers

V. Modulation of Polymer Properties Mechanochemical Processing
Use of Additives (Plasticizers, Stabilizers)
Blending

VI. Polymer Processing Techniques of Solid, Melt and Solution Processing
Mixing
Coating
Less-conventional Techniques

VII. Useful Forms of Polymeric Materials Fibers
Plastics
Rubbers
Composites

VIII. Polymer Applications Polymers as Core, Technological and Advanced Materials
Traditional Applications
Highly Specialized and Emerging Applications

IX. Biopolymers

LABORATORY COMPONENTS

I. Polymer Synthesis - Mechanisms and Techniques

Free Radical Polymerization (Solution & Bulk)
Emulsion Radical Polymerization
Free Radical Copolymerization
Anionic Polymerization
Cationic Polymerization
Solution Polycondensation
Interfacial Polycondensation
Bulk Polycondensation
Inorganic Polymers

II. Polymer Purification and Fractionation Vacuum Devolatilization
Phase Separation in Polymer Solutions
Extraction
Freeze Drying

III. Polymer Reaction and Modification Chain and Side Chain Hydrolysis
Side Chain Condensation of Natural Polymers
Crosslinking

IV. Polymer Characterization and Key Techniques Solution Properties - Viscometry and Gel Permeation Chromatography
Chain Structure - Spectroscopic Techniques (IR, NMR)
Thermal Transition - Thermal Microscopy and Differential Scanning Calorimetry
Degradation - Chemical Hydrolysis/Viscometry, Thermogravimetric Analysis
Polymer Morphology - Optical Microscopy, Electron Microscopy, X-Ray Diffraction

V. Structure Properties Relationships and Laboratory Scale Processing Melt-Rheology and Monofilament Extrusion
Stress-Strain Behavior of Molded Films and Oriented Monofilaments
Swelling of Cross-linked Polymers

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